The cloth of Sean Connery’s blue suit in Q’s lab in Goldfinger is quite mysterious. It is a heavy weight, has a mottled colouring and has a woollen texture. That means it’s most likely tweed. We get another look at the same Anthony Sinclair suit in Woman of Straw, and in this film—the suit’s original appearance—the suit is a three-piece. There’s no question it’s the same suit. The cut is the same button two with natural shoulders and a draped chest. It has swelled edges, cloth-covered buttons and jetted pockets. The vents are still a mystery. The poor lighting in this film makes the vent style difficult to make out, but I believe I see double vents. See the enhanced screenshot below.
The trousers have double forward pleats. The waistcoat is the same style as the waistcoats in Goldfinger: six buttons with five to button. Connery, however, fastens the bottom button, which is meant to be left open. This disrupts the otherwise clean lines of the waistcoat. The covered buttons down the waistcoat make a big impact, since without the waistcoat the covered buttons almost go unnoticed. Covered buttons aren’t ordinarily seen outside of formalwear, but they were popular in the 1960s on lounge suits as well. The Avengers’ John Steed also wore suits with covered buttons.
This is a town and country suit, meaning it can effectively transition between relaxed country wear and business. The cloth has a country texture in a city colour, and the jetted pockets are a more formal city touch. Even though this suit is appropriate in both the city and country, it fits in better here than it does in Q’s lab. The houndstooth suit that Bond wears in M’s office also seems more appropriate in this film.
Connery wears this suit a few times throughout Women of Straw. Early in the film he wears a solid light blue tie, tied in a four-in-hand knot just like he does in Goldfinger. The white or off-white shirt has a moderate spread collar, a placket and double cuffs. Later in the film he wears a solid black tie, also tied in a four-in-hand knot, and the white or off-white shirt has a wider spread collar like in Goldfinger. He wears a white pocket handkerchief with both outfits.